* Incorrect trop_mozart mechanism to be used only for pre-processor testing SPECIES Solution O3, O, O1D -> O, N2O, NO, NO2, NO3, HNO3, HO2NO2, N2O5, H2, OH, HO2, H2O2 CH4, CO, CH3O2, CH3OOH, CH2O, CH3OH, C2H5OH C2H4, EO -> HOCH2CH2O, EO2 -> HOCH2CH2O2, CH3COOH, GLYALD -> HOCH2CHO C2H6, C2H5O2, C2H5OOH, CH3CHO, CH3CO3, CH3COOOH C3H6, C3H8, C3H7O2, C3H7OOH, PO2 -> C3H6OHO2, POOH -> C3H6OHOOH CH3COCH3, RO2 -> CH3COCH2O2, ROOH -> CH3COCH2OOH BIGENE -> C4H8, ENEO2 -> C4H9O3 MEK -> C4H8O, MEKO2 -> C4H7O3, MEKOOH -> C4H8O3 BIGALK -> C5H12, ALKO2 -> C5H11O2, ALKOOH -> C5H12O2 ISOP -> C5H8, ISOPO2 -> HOCH2COOCH3CHCH2, ISOPOOH -> HOCH2COOHCH3CHCH2 MVK -> CH2CHCOCH3, MACR -> CH2CCH3CHO MACRO2 -> CH3COCHO2CH2OH, MACROOH -> CH3COCHOOHCH2OH MCO3 -> CH2CCH3CO3, HYDRALD -> HOCH2CCH3CHCHO, HYAC -> CH3COCH2OH CH3COCHO, XO2 -> HOCH2COOCH3CHOHCHO, XOOH -> HOCH2COOHCH3CHOHCHO C10H16, TERPO2 -> C10H17O3, TERPOOH -> C10H18O3 TOLUENE -> C7H8, CRESOL -> C7H8O, TOLO2 -> C7H9O5, TOLOOH -> C7H10O5 XOH -> C7H10O6, BIGALD -> C5H6O2, GLYOXAL -> C2H2O2 PAN -> CH3CO3NO2, ONIT -> CH3COCH2ONO2, MPAN -> CH2CCH3CO3NO2 ISOPNO3 -> CH2CHCCH3OOCH2ONO2, ONITR -> CH2CCH3CHONO2CH2OH CB1 -> C, CB2 -> C, OC1 -> C, OC2 -> C, SOA -> C12 SO2, DMS -> CH3SCH3, SO4, NH3, NH4, NH4NO3 SSLT01 -> NaCl, SSLT02 -> NaCl, SSLT03 -> NaCl, SSLT04 -> NaCl DST01 -> AlSiO5, DST02 -> AlSiO5, DST03 -> AlSiO5, DST04 -> AlSiO5 Rn, Pb HCN, CH3CN, C2H2, HCOOH, HOCH2OO End Solution Fixed M, N2, O2, H2O End Fixed Col-int O3 = 0. O2 = 0. End Col-int End SPECIES Solution Classes Explicit CH4, N2O, CO, Rn, Pb, H2, HCN, CH3CN End Explicit Implicit O3, O1D, O, NO, NO2, NO3, HNO3, HO2NO2, N2O5, OH, HO2, H2O2 CH3O2, CH3OOH, CH2O, CH3OH, C2H5OH C2H4, EO, EO2, CH3COOH, GLYALD C2H6, C2H5O2, C2H5OOH, CH3CHO, CH3CO3, CH3COOOH C3H6, C3H8, C3H7O2, C3H7OOH, PO2, POOH, CH3COCH3, RO2, ROOH BIGENE, ENEO2, BIGALK, ALKO2, ALKOOH, MEK, MEKO2, MEKOOH ISOP, ISOPO2, ISOPOOH, MVK, MACR, MACRO2, MACROOH, MCO3 HYDRALD, HYAC, CH3COCHO, XO2, XOOH C10H16, TERPO2, TERPOOH TOLUENE, CRESOL, TOLO2, TOLOOH, XOH, BIGALD, GLYOXAL PAN, ONIT, MPAN, ISOPNO3, ONITR SO2, DMS, SO4, NH3, NH4, NH4NO3, SOA CB1, CB2, OC1, OC2 C2H2, HCOOH, HOCH2OO SSLT01, SSLT02, SSLT03, SSLT04 DST01, DST02, DST03, DST04 End Implicit End Solution Classes CHEMISTRY Photolysis [jo2->,jo2_b] O2 + hv -> 2*O [jo1d->,jo3_a] O3 + hv -> O1D + O2 [jo3p->,jo3_b] O3 + hv -> O + O2 [jn2o] N2O + hv -> O1D + N2 [jno2] NO2 + hv -> NO + O [jn2o5->,jn2o5_a] N2O5 + hv -> NO2 + NO3 [jhno3] HNO3 + hv -> NO2 + OH [jno3_a] NO3 + hv -> .89*NO2 + .11*NO + .89*O3 [jno3_b] NO3 + hv -> .89*NO2 + .11*NO + .89*O3 [jho2no2_a] HO2NO2 + hv -> .33*OH + .33*NO3 + .66*NO2 + .66*HO2 [jho2no2_b] HO2NO2 + hv -> .33*OH + .33*NO3 + .66*NO2 + .66*HO2 [jch3ooh] CH3OOH + hv -> CH2O + HO2 + OH [jch2o_a] CH2O + hv -> CO + 2 * HO2 [jch2o_b] CH2O + hv -> CO + H2 [jh2o2] H2O2 + hv -> 2*OH [jch3cho] CH3CHO + hv -> CH3O2 + CO + HO2 [jpooh->,jch3ooh] POOH + hv -> CH3CHO + CH2O + HO2 + OH [jch3co3h->,.28*jh2o2] CH3COOOH + hv -> CH3O2 + OH + CO2 [jpan] PAN + hv -> .6*CH3CO3 + .6*NO2 + .4*CH3O2 + .4*NO3 + .4*CO2 [jmpan->,jpan] MPAN + hv -> MCO3 + NO2 [jmacr_a] MACR -> .67*HO2 + .33*MCO3 + .67*CH2O + .67*CH3CO3 + .33*OH + .67*CO [jmacr_b] MACR -> .67*HO2 + .33*MCO3 + .67*CH2O + .67*CH3CO3 + .33*OH + .67*CO [jmvk] MVK + hv -> .7*C3H6 + .7*CO + .3*CH3O2 + .3*CH3CO3 [jc2h5ooh->,jch3ooh] C2H5OOH + hv -> CH3CHO + HO2 + OH [jc3h7ooh->,jch3ooh] C3H7OOH + hv -> .82 * CH3COCH3 + OH + HO2 [jrooh->,jch3ooh] ROOH + hv -> CH3CO3 + CH2O + OH [jacet] CH3COCH3 + hv -> CH3CO3 + CH3O2 [jmgly] CH3COCHO + hv -> CH3CO3 + CO + HO2 [jxooh->,jch3ooh] XOOH + hv -> OH [jonitr->,jch3cho] ONITR + hv -> HO2 + CO + NO2 + CH2O [jisopooh->,jch3ooh] ISOPOOH + hv -> .402 * MVK + .288 * MACR + .69 * CH2O + HO2 [jhyac] HYAC + hv -> CH3CO3 + HO2 + CH2O [jglyald] GLYALD + hv -> 2 * HO2 + CO + CH2O [jmek->,jacet] MEK + hv -> CH3CO3 + C2H5O2 [jbigald->,.2*jno2] BIGALD + hv -> .45*CO + .13*GLYOXAL + .56*HO2 + .13*CH3CO3 + .18*CH3COCHO [jglyoxal->,jmgly] GLYOXAL + hv -> 2*CO + 2*HO2 [jalkooh->,jch3ooh] ALKOOH + hv -> .4*CH3CHO + .1*CH2O + .25*CH3COCH3 + .9*HO2 + .8*MEK + OH [jmekooh->,jch3ooh] MEKOOH + hv -> OH + CH3CO3 + CH3CHO [jtolooh->,jch3ooh] TOLOOH + hv -> OH + .45*GLYOXAL + .45*CH3COCHO + .9*BIGALD [jterpooh->,jch3ooh] TERPOOH + hv -> OH + .1*CH3COCH3 + HO2 + MVK + MACR End Photolysis Reactions * [usr_O_O2] O + O2 + M -> O3 + M * O + O3 -> 2*O2 ; 8e-12, -2060 [o1d_n2] O1D + N2 -> O + N2 ; 2.1e-11, 115 [o1d_o2] O1D + O2 -> O + O2 ; 3.2e-11, 70 [ox_l1] O1D + H2O -> 2*OH ; 2.2e-10 H2 + O1D -> HO2 + OH ; 1.1e-10 H2 + OH -> H2O + HO2 ; 2.8e-12, -1800 O + OH -> HO2 + O2 ; 2.2e-11, 120 HO2 + O -> OH + O2 ; 3e-11, 200 [ox_l2] OH + O3 -> HO2 + O2 ; 1.7e-12, -940 [ox_l3] HO2 + O3 -> OH + 2*O2 ; 1.e-14, -490 [usr_HO2_HO2] HO2 + HO2 -> H2O2 + O2 H2O2 + OH -> H2O + HO2 ; 2.9e-12, -160 OH + HO2 -> H2O + O2 ; 4.8e-11, 250 OH + OH -> H2O + O ; 1.8e-12 OH + OH + M -> H2O2 + M ; 6.9e-31,1., 2.6e-11,0., .6 N2O + O1D -> N2 + O2 ; 4.9e-11 N2O + O1D -> 2*NO ; 6.7e-11 [ox_p1] NO + HO2 -> NO2 + OH ; 3.5e-12, 250 NO + O3 -> NO2 + O2 ; 3e-12, -1500 NO2 + O -> NO + O2 ; 5.1e-12, 210 NO2 + O3 -> NO3 + O2 ; 1.2e-13, -2450 NO3 + HO2 -> OH + NO2 ; 3.5e-12 [tag_NO2_NO3] NO2 + NO3 + M -> N2O5 + M ; 2.e-30,4.4, 1.4e-12,.7, .6 [usr_N2O5_M] N2O5 + M -> NO2 + NO3 + M [tag_NO2_OH] NO2 + OH + M -> HNO3 + M ; 1.80e-30, 3.0, 2.8e-11, 0.0, 0.6 [usr_HNO3_OH] HNO3 + OH -> NO3 + H2O NO3 + NO -> 2*NO2 ; 1.5e-11, 170 [tag_NO2_HO2] NO2 + HO2 + M -> HO2NO2 + M ; 2.0e-31,3.4, 2.9e-12,1.1, .6 HO2NO2 + OH -> H2O + NO2 + O2 ; 1.3e-12, 380 [usr_HO2NO2_M] HO2NO2 + M -> HO2 + NO2 + M CH4 + OH -> CH3O2 + H2O ; 2.45e-12, -1775 CH4 + O1D -> .75*CH3O2 + .75*OH + .25*CH2O + .4*HO2 + .05*H2 ; 1.5e-10 [ox_p2] CH3O2 + NO -> CH2O + NO2 + HO2 ; 2.8e-12, 300 CH3O2 + CH3O2 -> 2 * CH2O + 2 * HO2 ; 5.e-13,-424 CH3O2 + CH3O2 -> CH2O + CH3OH ; 1.9e-14,706 CH3O2 + HO2 -> CH3OOH + O2 ; 4.1e-13, 750 CH3OOH + OH -> .7 * CH3O2 + .3 * OH + .3 * CH2O + H2O ; 3.8e-12, 200 CH2O + NO3 -> CO + HO2 + HNO3 ; 6.0e-13, -2058 CH2O + OH -> CO + H2O +HO2 ; 9.e-12 CO + OH + M -> CO2 + HO2 + M ; 5.90e-33, 1.4, 1.10e-12, -1.3, 0.6 [usr_CO_OH_b] CO + OH -> CO2 + HO2 CH3OH + OH -> HO2 + CH2O ; 7.3e-12,-620 HCOOH + OH -> HO2 + CO2 + H2O ; 4.5e-13 CH2O + HO2 -> HOCH2OO ; 9.7e-15, 625 HOCH2OO -> CH2O + HO2 ; 2.4e12, -7000 HOCH2OO + NO -> HCOOH + NO2 + HO2 ; 2.6e-12, 265 HOCH2OO + HO2 -> HCOOH ; 7.5e-13, 700 *C2 C2H2 + OH + M -> .65*GLYOXAL + .65*OH + .35*HCOOH + .35*HO2 ; 5.5e-30,0,8.3e-13,-2,.6 + .35*CO + M [tag_C2H4_OH] C2H4 + OH + M -> .75*EO2 + .5*CH2O + .25*HO2 + M ; 1.e-28,.8, 8.8e-12,0., .6 [ox_l6] C2H4 + O3 -> CH2O + .12*HO2 + .5*CO + .12*OH + .5*HCOOH ; 1.2e-14, -2630 [ox_p16] EO2 + NO -> EO + NO2 ; 4.2e-12,180 EO + O2 -> GLYALD + HO2 ; 1.e-14 EO -> 2 * CH2O + HO2 ; 1.6e11,-4150 C2H6 + OH -> C2H5O2 + H2O ; 8.7e-12, -1070 [ox_p5] C2H5O2 + NO -> CH3CHO + HO2 + NO2 ; 2.6e-12, 365 C2H5O2 + HO2 -> C2H5OOH + O2 ; 7.5e-13, 700 C2H5O2 + CH3O2 -> .7 * CH2O + .8 * CH3CHO + HO2 ; 2.e-13 + .3 * CH3OH + .2 * C2H5OH C2H5O2 + C2H5O2 -> 1.6 * CH3CHO + 1.2 * HO2 + .4 * C2H5OH ; 6.8e-14 C2H5OOH + OH -> .5 * C2H5O2 + .5 * CH3CHO + .5 * OH ; 3.8e-12, 200 CH3CHO + OH -> CH3CO3 + H2O ; 5.6e-12, 270 CH3CHO + NO3 -> CH3CO3 + HNO3 ; 1.4e-12, -1900 [ox_p4] CH3CO3 + NO -> CH3O2 + CO2 + NO2 ; 8.1e-12, 270 [tag_CH3CO3_NO2] CH3CO3 + NO2 + M -> PAN + M ; 8.5e-29,6.5, 1.1e-11,1., .6 CH3CO3 + HO2 -> .75*CH3COOOH + .25*CH3COOH + .25*O3 ; 4.3e-13, 1040 CH3CO3 + CH3O2 -> .9*CH3O2 + CH2O + .9*HO2 + .9*CO2 + .1*CH3COOH ; 2.0e-12,500 CH3COOOH + OH -> .5*CH3CO3 + .5*CH2O + .5*CO2 + H2O ; 1e-12 PAN + OH -> CH2O + NO3 + CO2 ; 4.e-14 [usr_PAN_M] PAN + M -> CH3CO3 + NO2 + M CH3CO3 + CH3CO3 -> 2*CH3O2 + 2*CO2 ; 2.5e-12, 500 GLYALD + OH -> HO2 + .2*GLYOXAL + .8*CH2O + .8*CO2 ; 1.e-11 GLYOXAL + OH -> HO2 + CO + CO2 ; 1.1e-11 CH3COOH + OH -> CH3O2 + CO2 + H2O ; 7.e-13 C2H5OH + OH -> HO2 + CH3CHO ; 6.9e-12,-230 *C3 [tag_C3H6_OH] C3H6 + OH + M -> PO2 + M ; 8.e-27,3.5, 3.e-11,0, .5 [ox_l4] C3H6 + O3 -> .54*CH2O + .19*HO2 + .33*OH ; 6.5e-15, -1900 + .08*CH4 + .56*CO + .5*CH3CHO + .31*CH3O2 + .25*CH3COOH C3H6 + NO3 -> ONIT ; 4.6e-13,-1156 [ox_p3] PO2 + NO -> CH3CHO + CH2O + HO2 + NO2 ; 4.2e-12, 180 PO2 + HO2 -> POOH + O2 ; 7.5e-13, 700 POOH + OH -> .5*PO2 + .5*OH + .5*HYAC + H2O ; 3.8e-12, 200 C3H8 + OH -> C3H7O2 + H2O ; 1.0e-11, -665 [ox_p9] C3H7O2 + NO -> .82 * CH3COCH3 + NO2 + HO2 + .27 * CH3CHO ; 4.2e-12, 180 C3H7O2 + HO2 -> C3H7OOH + O2 ; 7.5e-13, 700 C3H7O2 + CH3O2 -> CH2O + HO2 + .82 * CH3COCH3 ; 3.75e-13, -40 C3H7OOH + OH -> H2O + C3H7O2 ; 3.8e-12, 200 [usr_CH3COCH3_OH] CH3COCH3 + OH -> RO2 + H2O [ox_p10] RO2 + NO -> CH3CO3 + CH2O + NO2 ; 2.9e-12, 300 RO2 + HO2 -> ROOH + O2 ; 8.6e-13, 700 RO2 + CH3O2 -> .3*CH3CO3 + .8*CH2O + .3*HO2 + .2*HYAC ; 7.1e-13, 500 + .5*CH3COCHO + .5*CH3OH ROOH + OH -> RO2 + H2O ; 3.8e-12, 200 ONIT + OH -> NO2 + CH3COCHO ; 6.8e-13 CH3COCHO + OH -> CH3CO3 + CO + H2O ; 8.4e-13,830 CH3COCHO + NO3 -> HNO3 + CO + CH3CO3 ; 1.4e-12, -1860 HYAC + OH -> CH3COCHO + HO2 ; 3.e-12 *C4 BIGENE + OH -> ENEO2 ; 5.4e-11 [ox_p15] ENEO2 + NO -> CH3CHO + .5*CH2O + .5*CH3COCH3 + HO2 + NO2 ; 4.2e-12, 180 MEK + OH -> MEKO2 ; 2.3e-12, -170 [ox_p17] MEKO2 + NO -> CH3CO3 + CH3CHO + NO2 ; 4.2e-12, 180 MEKO2 + HO2 -> MEKOOH ; 7.5e-13, 700 MEKOOH + OH -> MEKO2 ; 3.8e-12, 200 MPAN + OH + M -> .5*HYAC + .5*NO3 + .5*CH2O + .5*HO2 ; 8.e-27,3.5,3.e-11,0.,.5 + .5*CO2 + M *C5 [soa5] BIGALK + OH -> ALKO2 ; 3.5e-12 [ox_p14] ALKO2 + NO -> .4*CH3CHO + .1*CH2O + .25*CH3COCH3 + .9*HO2 ; 4.2e-12, 180 + .75*MEK + .9*NO2 + .1*ONIT ALKO2 + HO2 -> ALKOOH ; 7.5e-13, 700 ALKOOH + OH -> ALKO2 ; 3.8e-12, 200 ISOP + OH -> ISOPO2 ; 2.54e-11, 410 [ox_l5] ISOP + O3 -> .4 * MACR + .2 * MVK + .07 * C3H6 + .27 * OH ; 1.05e-14, -2000 + .06 * HO2 + .6 * CH2O + .3 * CO + .1 * O3 + .2 * MCO3 + .2 * CH3COOH [ox_p6] ISOPO2 + NO -> .08 * ONITR + .92 * NO2 + HO2 + .55 * CH2O ; 4.4e-12, 180 + .23 * MACR + .32 * MVK + .37 * HYDRALD ISOPO2 + NO3 -> HO2 + NO2 + .6 * CH2O + .25 * MACR ; 2.4e-12 + .35 * MVK + .4 * HYDRALD ISOPO2 + HO2 -> ISOPOOH ; 8.e-13, 700 ISOPOOH + OH -> .8 * XO2 + .2 * ISOPO2 ; 1.52e-11, 200 ISOPO2 + CH3O2 -> .25 * CH3OH + HO2 + 1.2 * CH2O ; 5.e-13,400 + .19 * MACR + .26 * MVK + .3 * HYDRALD ISOPO2 + CH3CO3 -> CH3O2 + HO2 + .6 * CH2O + CO2 ; 1.4e-11 + .25 * MACR + .35 * MVK + .4 * HYDRALD ISOP + NO3 -> ISOPNO3 ; 3.03e-12,-446 ISOPNO3 + NO -> 1.206 * NO2 + .794 * HO2 + .072 * CH2O + .167 * MACR ; 2.7e-12, 360 + .039 * MVK + .794 * ONITR ISOPNO3 + NO3 -> 1.206 * NO2 + .072 * CH2O + .167 * MACR + .039 * MVK ; 2.4e-12 + .794 * ONITR + .794 * HO2 ISOPNO3 + HO2 -> .206 * NO2 + .794 * HO2 + .008 * CH2O ; 8.e-13, 700 + .167 * MACR + .039 * MVK + .794 * ONITR MVK + OH -> MACRO2 ; 4.13e-12, 452 [ox_l7] MVK + O3 -> .8 * CH2O + .95 * CH3COCHO + .08 * OH + .2 * O3 ; 7.52e-16,-1521 + .06 * HO2 + .05 * CO + .04 * CH3CHO MACR + OH -> .5 * MACRO2 + .5 * H2O + .5 * MCO3 ; 1.86e-11, 175 [ox_l8] MACR + O3 -> .8 * CH3COCHO + .275 * HO2 + .2 * CO + .2 * O3 ; 4.4e-15, -2500 + .7 * CH2O + .215 * OH [ox_p7] MACRO2 + NO -> NO2 + .47 * HO2 + .25 * CH2O ; 2.7e-12, 360 + .25 * CH3COCHO + .53 * CH3CO3 + .53 * GLYALD + .22 * HYAC + .22 * CO MACRO2 + NO -> 0.8*ONITR ; 1.3e-13,360 MACRO2 + NO3 -> NO2 + .47*HO2 + .25*CH2O + .25*CH3COCHO ; 2.4e-12 + .22*CO + .53*GLYALD + .22*HYAC + .53*CH3CO3 MACRO2 + HO2 -> MACROOH ; 8.e-13, 700 MACRO2 + CH3O2 -> .73*HO2 + .88*CH2O + .11*CO + .24*CH3COCHO ; 5.e-13,400 + .26*GLYALD + .26*CH3CO3 + .25*CH3OH + .23*HYAC MACRO2 + CH3CO3 -> .25*CH3COCHO + CH3O2 + .22*CO + .47*HO2 + CO2 ; 1.4e-11 + .53*GLYALD + .22*HYAC + .25*CH2O + .53*CH3CO3 MACROOH + OH -> .5 * MCO3 + .2*MACRO2 + .1*OH + .2*HO2 ; 2.3e-11, 200 [ox_p8] MCO3 + NO -> NO2 + CH2O + CH3CO3 + CO2 ; 5.3e-12, 360 MCO3 + NO3 -> NO2 + CH2O + CH3CO3 + CO2 ; 5.e-12 MCO3 + HO2 -> .25*O3 + .25*CH3COOH + .75*CH3COOOH + .75*O2 ; 4.30e-13, 1040 MCO3 + CH3O2 -> 2 * CH2O + HO2 + CO2 + CH3CO3 ; 2.0e-12,500 MCO3 + CH3CO3 -> 2 * CO2 + CH3O2 + CH2O + CH3CO3 ; 4.6e-12, 530 MCO3 + MCO3 -> 2 * CO2 + 2 * CH2O + 2 * CH3CO3 ; 2.3e-12, 530 [usr_MCO3_NO2] MCO3 + NO2 + M -> MPAN + M [usr_MPAN_M] MPAN + M -> MCO3 + NO2 + M ONITR + OH -> HYDRALD + .4*NO2 + HO2 ; 4.5e-11 ONITR + NO3 -> HYDRALD + NO2 + HO2 ; 1.4e-12, -1860 HYDRALD + OH -> XO2 ; 1.86e-11,175 [ox_p11] XO2 + NO -> NO2 + HO2 + .5*CO + .25*GLYOXAL ; 2.7e-12, 360. + .25*HYAC + .25*CH3COCHO + .25*GLYALD XO2 + NO3 -> NO2 + HO2 + 0.5*CO + .25*HYAC ; 2.40e-12 + 0.25*GLYOXAL + .25*CH3COCHO + .25*GLYALD XO2 + HO2 -> XOOH ; 8.e-13, 700 XO2 + CH3O2 -> .3 * CH3OH + 0.8*HO2 + .7 * CH2O ; 5.00e-13, 400. + .2 * CO + .1 * HYAC + .1*GLYOXAL + .1 * CH3COCHO + .1 * GLYALD XO2 + CH3CO3 -> 0.5*CO + CH3O2 + HO2 + CO2 + .25 GLYOXAL ; 1.30e-12, 640. + .25 * HYAC + .25 * CH3COCHO + .25 * GLYALD XOOH + OH -> H2O + XO2 ; 1.90e-12, 190 [usr_XOOH_OH] XOOH + OH -> H2O + OH *C7 [soa4] TOLUENE + OH -> .25*CRESOL + .25*HO2 + .7*TOLO2 ; 1.7e-12, 352 CRESOL + OH -> XOH ; 3.e-12 XOH + NO2 -> .7*NO2 + .7*BIGALD + .7*HO2 ; 1.e-11 [ox_p12] TOLO2 + NO -> .45*GLYOXAL + .45*CH3COCHO +.9*BIGALD ; 4.2e-12, 180 + .9*NO2 + .9*HO2 TOLO2 + HO2 -> TOLOOH ; 7.5e-13, 700 TOLOOH + OH -> TOLO2 ; 3.8e-12, 200 *C10 [soa2] C10H16 + OH -> TERPO2 ; 1.2e-11, 444 [soa1] C10H16 + O3 -> .7*OH + MVK + MACR + HO2 ; 1.e-15, -732 [soa3] C10H16 + NO3 -> TERPO2 + NO2 ; 1.2e-12, 490 [ox_p13] TERPO2 + NO -> .1*CH3COCH3 + HO2 + MVK + MACR + NO2 ; 4.2e-12, 180 TERPO2 + HO2 -> TERPOOH ; 7.5e-13, 700 TERPOOH + OH -> TERPO2 ; 3.8e-12, 200 Rn -> Pb ; 2.1e-6 *het/aerosol rxns [usr_N2O5_aer] N2O5 -> 2 * HNO3 [usr_NO3_aer] NO3 -> HNO3 [usr_NO2_aer] NO2 -> 0.5*OH + 0.5*NO + 0.5*HNO3 CB1 -> CB2 ; 7.1e-6 [usr_SO2_OH] SO2 + OH -> SO4 DMS + OH -> SO2 ; 9.6e-12,-234. [usr_DMS_OH] DMS + OH -> .5 * SO2 + .5 * HO2 DMS + NO3 -> SO2 + HNO3 ; 1.9e-13, 520. NH3 + OH -> H2O ; 1.7e-12, -710. OC1 -> OC2 ; 7.1e-6 [usr_HO2_aer] HO2 -> 0.5*H2O2 *cyanides HCN + OH + M -> HO2 + M ; 4.28e-33, 0.0, 9.30e-15, -4.42, 0.8 CH3CN + OH -> HO2 ;7.8e-13, -1050 End Reactions Ext Forcing NO <- dataset CO <- dataset SO2 <- dataset End Ext Forcing END CHEMISTRY SIMULATION PARAMETERS Version Options model = cam machine = intel architecture = hybrid vec_ftns = on multitask = on namemod = on modules = on End Version Options END SIMULATION PARAMETERS